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SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 08/06/2003 Version 1.11 Section 1 - Product and Company Information Product Name CHLOROFORM, 99.9%, A.C.S. Diethenyl-benzene polymer with ethenylbenzene and ethenylethylbenzene, sulfonated 69011-20-7 New Jersey Right To Know Components Water CAS-No. Risk of serious damage to eyes. 453/2010 Version 6.0 Revision Date 28.07.2015 Print Date 18.03.2017 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : 1,1'-(Isopropylidene)bis[3,5-dibromo-4-(2,3-dibromopropoxy)benzene] Product Number : S509574 Brand : Aldrich CAS-No. See 29CFR 1910.1028 . E12508 www.sigma-aldrich.com Page 7. Benzene CAS RN: 71-43-2 Stability / Shelf Life . P271 Use only outdoors or in a well-ventilated area. 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. 3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES Telephone : +1 314 771-5765 Fax : +1 800 325-5052 . Sigma-Aldrich - 270709 Page 1 of 9 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 5.0 Revision Date 04/27/2012 Print Date 07/06/2012 1. The capability of superhalogen induced ionization of benzene molecules has been reported based on ab initio calculations. Apply water from as far a distance as possible. PRODUCT AND COMPANY IDENTIFICATION Product name : Benzene Product Number : 12540 Brand : Fluka Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Synonyms Benzene, vinyl- * Cinnamene * Ethenylbenzene * Ethylene, phenyl- * NCI-C02200 * Phenethylene * . SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 08/18/2003 Version 1.4 . Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. HAZARDOUS DECOMPOSITION PRODUCTS SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.2 Revision Date 06/25/2014 Print Date 11/06/2018 1. Uses advised against Food, drug, pesticide or biocidal product use. : 4422-95-1 P270 Do not eat, drink or smoke when using this product. Product name : Residual Solvent - Benzene Product Number : PHR1318 Brand : Sigma-Aldrich 1.2 Relevant identified uses of the substance or mixture and uses advised against . May cause sensitization by inhalation and skin contact. . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.5 Revision Date 12/11/2014 Print Date 06/28/2019 1. Aldrich - B57702 Page 1 of 7 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.2 Revision Date 01/17/2012 Print Date 02/23/2012 1. Where legally required, the SDS contains an Annex with exposure scenarios. Sigma-Aldrich - 324558 Page 1 of 7 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 5.0 Revision Date 04/21/2012 Print Date 05/23/2012 1. M80806 www.sigma-aldrich.com Page 5. E26266 www.sigma-aldrich.com Page 7. Sigma-Aldrich - 401765 Page1 of 9 SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET according to Regulation (EC) No. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 09/02/2002 . Key Info; Identification; Protective Equipment / Clothing; Protective Distance; . Risk of serious damage to eyes. Eyes Causes eye burns. PRODUCT AND COMPANY IDENTIFICATION Product name : Acetone Product Number : 650501 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA View all locations and contact information. Skip Data Menu. . (Benzene, ethenyl-, homopolymer) ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Benzene 71-43-2 S- 0.0300 In urine ACGIH - Biological . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.9 Revision Date 08/10/2016 Print Date 03/02/2017 1. 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. 3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES Telephone : +1 314 771-5765 Fax : +1 800 325-5052 . 247642 www.sigma-aldrich.com Page 7. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 09/04/2002 Version 1.4 Section 1 - Product and Company Information Product Name 2,2,4-TRIMETHYLPENTANE, 99.7+%,HPLC GRADE . PRODUCT AND COMPANY IDENTIFICATION Product name : Sulfuric acid Product Number : 339741 Brand : Aldrich Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA . PRODUCT AND COMPANY IDENTIFICATION Product name : Bromobenzene Product Number : B57702 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Materials to Avoid: Strong oxidizing agents. PRODUCT AND COMPANY IDENTIFICATION Product name : Caffeine Product Number : C0750 Brand : Sigma-Aldrich Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA . Risk Statements: Harmful by inhalation. Sigma-Aldrich - 650501 Page 1 of 8 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 3.9 Revision Date 04/21/2012 Print Date 05/21/2012 1. benzene * Dimethylaniline (ACGIH:OSHA) * N,N-Dimethylaniline (OSHA) * . 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Israel Ltd. 3 PARK RABIN, PLAUT 7670603 REHOVOT ISRAEL Telephone : +972 8948-4222 Product name : (Diacetoxyiodo)benzene Product Number : 178721 Brand : Aldrich CAS-No. : 4422-95-1 Section 12 - Ecological Information Section 13 - Disposal Considerations . Synonyms Benzene, dimethyl- * Dimethylbenzene (OSHA) * Ksylen (Polish) * Methyl toluene * NCI-C55232 * . SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 02/26/2007 Date Updated: 01/29/2006 . Skin May be harmful if absorbed through skin. SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.0 Revision Date 07/28/2010 Print Date 06/21/2012 1. Merck & Co., Inc., Rahway, NJ, USA is known as MSD outside of the United States and Canada. Detergent HD-90 * Dodecyl benzene sodium . : 270573-71-2 Close valve after each use and when empty. P273 Avoid release to the environment. UNITED STATES REGULATORY INFORMATION SARA LISTED: No TSCA INVENTORY ITEM: Yes . As of December 1, 2010 all Safety Data Sheets of hazardous substances are provided according to the requirements of CLP (Regulation (EC) No 1272/2008, adopting GHS) and Annex II of REACH (Regulation (EC) 1907/2006). SAFETY DATA SHEET Creation Date 16-Apr-2012 Revision Date 25-Dec-2021 Revision Number 4 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers . PRODUCT AND COMPANY IDENTIFICATION . BENZENE SLIGHTLY IN ETHER N/A = not available Section 10 - Stability and Reactivity . about it in the material safety data sheet. Causes burns. world class partners Merck Millipore + Sigma-Aldrich = the life science business of Merck Operating in the U.S. & Canada as MilliporeSigma. P264 Wash hands thoroughly after handling. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 08/13/2007 Date Updated: 01/31/2006 Version 1.7 Section 1 - Product and Company Information Product Name MERCURY(II) CHLORIDE, REAGENTPLUS TM, 99.5% Product Number M1136 Brand SIAL Company Sigma-Aldrich Canada, Ltd : 4506-66-5 The final benzene standard in 1910.1028 applies to all occupational exposures to benzene except some : 21850-44-2 1.2 Relevant identified uses . Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any PRODUCT AND COMPANY IDENTIFICATION . Use nonsparking tools. PRODUCT AND COMPANY IDENTIFICATION Product name : (2-Chloroethyl)benzene Product Number : C40405 Brand : Aldrich Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . Benzene is an organic chemical compound with the molecular formula C 6 H 6.The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Identification Product Name Cumene Cat No. Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number F005, U019, D018, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. SAFETY DATA SHEET Version 6.5 Revision Date 04/26/2022 Print Date 09/17/2022 . 1907/2006 Version 5.4 Revision Date 12.11.2014 . 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. Benzene-1,3,5-tricarbonyl chloride Trimesoyl chloride Formula : C 9 H 3 Cl 3 O 3 Molecular Weight : 265.48 g/mol CAS-No. Benzene 71-43-2 S- 0.0300 In urine ACGIH - Biological . SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 02/26/2007 Date Updated: 02/05/2006 . Material Safety Data Sheet or SDS for 1,2-Dichloroethane 100955 from Merck for download or viewing in the browser. ALDRICH - 240125 www.sigma-aldrich.com Page 8. Synonyms Benzene, 1-ethenyl-4-methyl- (9CI) * . Company Sigma-Aldrich Address 3050 Spruce Street SAINT LOUIS MO 63103 US Technical Phone: 800-325-5832 Fax: 800-325-5052 . Read and follow all Safety Data Sheets (SDS'S) before use. Synonyms Benzene, 1,1'-(1,2-ethanediyl)bis- * Dibenzyl * . PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 4.10 Revision Date 06/25/2014 Print Date 06/21/2016 1. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 09/02/2002 . Stable under recommended storage conditions. Disposal Methods. Safety Statements: In case of contact with eyes, rinse . Sigma- SML0837 Page 1 of 6 SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 6.1 Revision Date 05/28/2017 Print Date 11/16/2018 1. : 601-020-00-8 CAS-No. BENZENE MISCIBLE N/A = not available Section 10 - Stability and Reactivity STABILITY . SRP: The scientific literature for the use of contact lenses by industrial workers is inconsistent. Gloves must be inspected prior to use. Benzene-1,3-dicarboxylic acid * m-Benzenedicarboxylic acid * Isophthalate * Kyselina isoftalova (Czech) * m-Phthalic acid RTECS Number: NT2007000 Section 3 - Hazards Identification Benzene ignites in contact with powdered chromic anhydride. 270520 www.sigma-aldrich.com Page 5. classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. PRODUCT AND COMPANY IDENTIFICATION . Where legally required, the SDS contains an Annex with exposure scenarios. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 05/24/2004 Date Updated: 04/04/2004 . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 4.3 Revision Date 07/30/2014 Print Date 10/16/2018 1. ALDRICH - 289957 www.sigma-aldrich.com Page 5. system and skin. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : 1,3-Bis(1-isocyanato-1-methylethyl)benzene Product Number : 409502 Brand : Aldrich CAS-No. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. 3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES Telephone : +1 314 771-5765 Fax : +1 800 . SIGMA-ALDRICH _____ MATERIAL SAFETY DATA SHEET Date Printed: 11.02.2014 Date Updated: 11.07.2006 . Aldrich - 339741 Page 1 of 6 SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.0 Revision Date 03/14/2010 Print Date 10/08/2010 1. Sigma-Aldrich - 270709 Page 5 of 10 Phenylmerca pturic acid mg/g Exposure Indices P264 Wash skin thouroughly after handling. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : 1,2-Bis(diphenylphosphino)benzene Product Number : 460273 Brand : Aldrich CAS-No. SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.3 Revision Date 08/04/2016 Print Date 01/23/2017 1. BENZENE CHLOROFORM N/A = not available Section 10 - Stability and Reactivity STABILITY Stable: Stable. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon.. Benzene is a natural constituent of crude oil and is one of the elementary petrochemicals. Benzene is a six membered aromatic compound. Aldrich - 172553 Page1 of 7 SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.2 Revision Date 06/27/2014 Print Date 06/23/2016 1. Potential Health Effects Inhalation May be harmful if inhaled. 1,2-Dichloroethane SDS Safety Data Sheet for 1,2-Dichloroethane 100955. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 02/12/2004 Version 1.2 . . MATERIAL SAFETY DATA SHEET Date Printed: 05.02.2013 Date Updated: 16.12.2009 . National Institute for Occupational Safety and Health Where high vapor concn are unavoidable, forced air masks should be used. Safety Statements: Keep away from sources of . : 932-87-6 1.2 Relevant identified uses of the substan ce or mixture and uses advised . PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Benzene -1,2 dithiol Product Number : 270865 Brand : Aldrich CAS-No. : 13991-08-7 1.2 Relevant identified uses of the substan ce or mixture and . SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 09/02/2002 . 3-5 D-76185 Karlsruhe Germany Telephone: +49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: sicherheit@carlroth.de Website: www.carlroth.de Competent person responsible for the safety data sheet: Department Health, Safety and Environment If there is a possibility of benzene exposure, even when the benzene . : 3240-34-4 1.2 Relevant identified uses of the substance or mixture and uses advised against . Other Solvents: BENZENE, TOLUENE, XYLENE CHLOROFORM, ETHER CARBON N/A = not available SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 4.7 Revision Date 06/30/2014 Print Date 10/01/2016 1. Chemical Product and Company Identification: MSDS Name: Benzene Catalog Numbers: AC167660000, AC167660010, AC167660025, AC167660250, AC167665000, AC168650250, AC295330000, . Causes skin burns. : 4481-30-5 1.2 Relevant identified uses of the substan ce or mixture and uses . SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.1 Revision Date 06/25/2014 Print Date 02/09/2017 1. Synonyms Arctuvin * Benzene, p-dihydroxy- * p-Benzenediol . REAGENT Product Number 319953 Brand ALDRICH Company Sigma-Aldrich Street Address 3050 Spruce Street . [ 15] Application Benzene may be used in the following processes: RESULTS . PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : 4,5 -Dihydroxy 1,3 benzenedisulfonic acid disodium salt monohydrate Product Number : 172553 Brand : Aldrich CAS-No. [ 60] Benzene, a commonly used industrial solvent is also an air pollutant and a potent carcinogen. 1907/2006 Version 6.4 Revision Date 27.01.2020 Print Date 02.09.2020 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : FAK Inhibitor 14 Product Number : SML0837 Brand : Sigma CAS-No. : 71-43-2 . Benzene CAS RN: 71-43-2 Other Preventive Measures. Benzene, diethenyl-, polymer with ethenylbenzene and ethenylethylbenzene, chloromethylated, trimethylamine-quaternized, hydroxide : 2778-42-9 1.2 Relevant identified uses of the substan ce or mixture . As of December 1, 2010 all Safety Data Sheets of hazardous substances are provided according to the requirements of CLP (Regulation (EC) No 1272/2008, adopting GHS) and Annex II of REACH (Regulation (EC) 1907/2006). PRODUCT AND COMPANY IDENTIFICATION Product name : Toluene Product Number : 179418 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. National Institute for Occupational Safety and Health Where there is a possibility of benzene contact to eyes or skin, safety showers, eye-wash fountains, and cleansing facilities shall be installed and maintained. SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 5.6 Revision Date 08/09/2016 Print Date 02/21/2017 1.

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